Saturday, December 8, 2012

Silicon

Silicon

General properties
Name, symbol, number silicon, Si, 14
Element category metalloid
Group, period, block 14, 3, p
Standard atomic weight 28.085(1)
Electron configuration [Ne] 3s2 3p2
2, 8, 4
History
Prediction Antoine Lavoisier (1787)
Discovery Jöns Jacob Berzelius (1824)
First isolation Jöns Jacob Berzelius (1824)
Named by Thomas Thomson (1831)

Silicon, a tetravalent metalloid, is a chemical element with the symbol Si and atomic number 14. It is less reactive than its chemical analog carbon, the nonmetal directly above it in the periodic table, but more reactive than germanium, the metalloid directly below it in the table. Controversy about silicon's character dates to its discovery: silicon was first prepared and characterized in pure form in 1824, and given the name silicium (from Latin: silicis, flints), with an -ium word -ending to suggest a metal, a name which the element retains in several non-English languages. However, its final English name, suggested in 1831, reflects the more physically similar elements carbon and boron.

Silicon is the eighth most common element in the universe by mass, but very rarely occurs as the pure free element in nature. It is most widely distributed in dusts, sands, planetoids, and planets as various forms of silicon dioxide (silica) or silicates. Over 90% of the Earth's crust is composed of silicate minerals, making silicon the second most abundant element in the Earth's crust (about 28% by mass) after oxygen.

Most silicon is used commercially without being separated, and indeed often with little processing of compounds from nature. These include direct industrial building-use of clays, silica sand and stone. Silica is used in ceramic brick. Silicate goes into Portland cement for mortar and stucco, and when combined with silica sand and gravel, to make concrete. Silicates are also in white ware ceramics such as porcelain, and in traditional quartz-based soda-lime glass. More modern silicon compounds such as silicon carbide form abrasives and high-strength ceramics. Silicon is the basis of the ubiquitous synthetic silicon-based polymers called silicones.

Elemental silicon also has a large impact on the modern world economy. Although most free silicon is used in the steel refining, aluminum-casting, and fine chemical industries (often to make fumed silica), the relatively small portion of very highly purified silicon that is used in semiconductor electronics (< 10%) is perhaps even more critical. Because of wide use of silicon in integrated circuits, the basis of most computers, a great deal of modern technology depends on it.

Silicon is an essential element in biology, although only tiny traces of it appear to be required by animals, however various sea sponges as well as microorganisms like diatoms need silicon in order to have structure. It is much more important to the metabolism of plants, particularly many grasses.

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