Saturday, December 29, 2012

Hafnium

Hafnium

General properties
Name, symbol, number hafnium, Hf, 72
Element category transition metal
Group, period, block 4, 6, d
Standard atomic weight 178.49
Electron configuration [Xe] 4f14 5d2 6s2
2, 8, 18, 32, 10, 2
History
Prediction Dmitri Mendeleev (1869)
Discovery Dirk Coster and George de Hevesy (1922)
First isolation Dirk Coster and George de Hevesy (1922)

Hafnium is a chemical element with the symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in zirconium minerals. Its existence was predicted by Dmitri Mendeleev in 1869. Hafnium was the penultimate stable isotope element to be discovered (rhenium was identified two years later). Hafnium is named after Hafnia, the Latin name for "Copenhagen", where it was discovered.

Hafnium is used in filaments and electrodes. Some semiconductor fabrication processes use its oxide for integrated circuits at 45 nm and smaller feature lengths. Some superalloys used for special applications contain hafnium in combination with niobium, titanium, or tungsten.

Hafnium's large neutron capture cross-section makes it a good material for neutron absorption in control rods in nuclear power plants, but at the same time requires that it be removed from the neutron-transparent corrosion-resistant zirconium alloys used in nuclear reactors.

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